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Research Publications (Water and Wastewater Technology)

Permanent URI for this collectionhttp://ir-dev.dut.ac.za/handle/10321/841

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Author: search.filters.author.Nayunigari, Mithil Kumar

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    Sorption isotherms, kinetic and optimization process of amino acid proline based polymer nanocomposite for the removal of selected textile dyes from industrial wastewater
    (Elsevier, 2016-10-18) Raghunath, Sharista; Anand, Krishnan; Gengan, Robert Moonsamy; Nayunigari, Mithil Kumar; Maity, Arjun
    In this article, adsorption and kinetic studies were carried out on three textile dyes, namely Reactive Blue 222 (RB 222), Reactive Red 195 (RR 195) and Reactive Yellow 145 (RY 145). The dyes studied in a mixture were adsorbed under various conditions onto PRO-BEN, a bentonite modified with a new cationic proline polymer (L-proline-epichlorohydrin polymer). The proline polymer was characterized by 1H NMR, Fourier transform infrared spec-troscopy (FT-IR), dynamic light scattering (DLS) and TEM. The PRO-BEN composite was characterized by FT-IR, dynamic light scattering (DLS) (zeta potential), TEM imaging, SEM/EDX and X-ray photoelectron spectroscopy (characterize the binding energy). During adsorption studies, factors involving pH, temperature, the initial con-centrations of the dyes and the quantity of PRO-BEN used during adsorption were established. The results re-vealed that the adsorption mechanism was categorized by the Langmuir type 1 isotherm. The adsorption data followed the pseudo-second order kinetic model. The intraparticle diffusion model indicated that adsorption did not only depend on the intraparticle diffusion of the dyes. The thermodynamic parameters verified that the adsorption process was spontaneous and exothermic. The Gibbs free energy values indicated that physisorption had occurred. Successful adsorption of dyes from an industrial effluent was achieved. Desorption studies concluded that PRO-BEN desorbed the dyes better than alumina. This can thereby be viewed as a recycla-ble remediation material. The PRO-BEN composite could be a cost efficient alternative towards the removal of or-ganic dyes in wastewater treatment.
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    Synthesis and performance evaluation of a new polymeric composite for the treatment of textile wastewater
    (ACS Publications, 2015) Gupta, Sanjay Kumar; Nayunigari, Mithil Kumar; Misra, Rohit; Ansari, Faiz Ahmad; Dionysiou, Dionysios (Dion) D.; Maity, Arjun; Bux, Faizal
    Azo dyes are synthetic colorants widely used in textile industry and are considered to be major contaminants in dye wastewater. Coagulation−flocculation is most preferred techniques to treat dye wastewater. A N,N-diisopropylamine-based new polymer was synthesized by polycondensation of epichlorohydrin, N,N-diisopropylamine, and ethylinediamine. The chemical and thermal properties of the polymer were investigated by FTIR, XRD, TGA, and viscosity measurements. The flocculation efficiency of the polymer was evaluated at different coagulant dose, organic load, and pH. The flocculation efficiency of this polymer was found to be higher over a pH range of 2−10 at its optimal dose of 80 mg/L. Morphological changes in the floc were studied by light and scanning electron microscopy. The zeta potential results clearly indicated that flocculation at the optimum doses is the result of charge neutralization and adsorption bridging. This study demonstrates the successful synthesis of the polymer, its excellent color removal efficiency (>98%) at lower doses, and effectiveness in dye wastewater treatment.