Theses and dissertations (Engineering and Built Environment)

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Aerobic sequencing batch reactor for the treatment of industrial wastewater from the brewery
(2017) Shabangu, Khaya Pearlman; Chetty, Maggie; Bakare, Babatunde F.
One of the major effects of socio-economic change due to industrialisation is the generation of industrial wastewater, which requires treatment before being released into the environment. Laboratory-scale aerobic sequencing batch reactors under suspended-growth heterotrophic activated sludge were operated in different aeration configurations to study their effect on the treatment of wastewater generated by a local brewery. The main purpose of this study was to evaluate the performance of the two laboratory-scale aerobic sequencing batch reactors treating brewery wastewater under continuous low-oxygen dosing concentration and cyclic aeration schemes on SBR operation. The characterisation of brewery wastewater was undertaken to assess the physicochemical composition of the wastewater produced from one of the breweries in South Africa (SAB). The data showed distinctive characteristics of brewery wastewater, which coincided with studies previously carried out on characterisation of brewery wastewater. The COD average concentration of the brewery influent was 7100 mg/L, with average pH values of 7. The BOD and the total solids content of the brewery wastewater influent from the facility were both high, implying that the influent was very rich in organic content and its discharge into water-receiving bodies or the municipal treatment plant could have adverse effects. From these results, a need for a competitive treatment technology was clearly highlighted so as to carry out a feasible treatment of the influent for the brewery industry. The aerobic sequencing batch reactors were designed, fabricated and set up for laboratory-scale treatment of wastewater from the brewery for 15 weeks. The performance of the two SBR configurations was determined with reference to COD, BOD, TS, VS and TSS. The experimental results demonstrated that wastewater generated from the breweries can be treated successfully using both aeration configurations. The results obtained indicated that treatment efficiencies in terms of COD and BOD were 94 % and 85 % respectively, for the reactor operated under continuous aeration configuration, while 81 % and 65 % was achieved for the reactor operated in the cyclic aeration scheme. The findings from this study demonstrate that the performance of the reactor operated under the continuous aeration scheme was successful, and showed statistically significant differences from the performance of the reactor operated under cyclic aeration schemes. These findings imply that there is a potential for the equipment, including financial benefit as a result of operating aerobic sequencing batch reactors for treating brewery wastewater under continuous low-oxygen concentration dosing schemes. In this study, it was also established that the maximum COD removal could be reached at an optimum hydraulic retention times of 5 days for both reactors. This was based upon viewing the experimental data; it appeared that the most significant difference in percentage COD removal was for HRTs 3 days and 4 days. Although, due to less percentage COD removal observed from HRTs 5 days till 7 days, it was hence established that the optimum removal of high strength organics in the brewery wastewater could be achieved within 5 days of treatment time. The pH adapted at an average of 7 for all batch experimentations of the study. The temperature maintained an average of 23 oC ambient, throughout the experimental period. These physical parameters ensured that the microbial population was kept healthy, without inhibiting its biological degradation activity. Although, sludge build up was observed in both aerobic SBRs on completion of each batch operation due to solids retention and organic pollutants biodegradation from the brewery wastewater. It was perceived that frequently reseeding both aerobic SBRs, as an alternative to 28 days sludge retention time would enhance the recovery of biomass, thus improving the overall removal of TSS consequently minimising sludge bulking in both reactors.
Anaerobic co-digestion of agricultural biomass with industrial wastewater for biogas production
(2021-03-26) Armah, Edward Kwaku; Chetty, Maggie; Deenadayalu, Nirmala
With the increasing demand for clean and affordable energy which is environmentally friendly, the use of renewable energy sources is a way for future energy generation. South Africa, like most countries in the world are over-dependent on the use of fossil fuels, prompting most current researchers to seek an affordable and reliable source of energy which is also,a focal point of the United Nations Sustainable Development Goal 7. In past decades, the process of anaerobic digestion (AD) also referred to as monodigestion, has proven to be efficient with positive environmental benefits for biogas production for the purpose of generating electricity, combined heat and power. However, due to regional shortages, process instability and lower biogas yield, the concept of anaerobic co-digestion (AcoD) emerged to account for these drawbacks. Given the considerable impact that industrial wastewater (WW) could provide nutrients in anaerobic biodigesters, the results of this study could apprise decisionmakers and the government to further implement biogas installations as an alternative energy source. The study aims at optimising the biogas production through AcoD of the agricultural biomasses: sugarcane bagasse (SCB) and corn silage (CS) with industrial WW sourced from Durban, KwaZulu-Natal, South Africa. The study commenced with the characterisation of the biomasses under this study with proximate and ultimate analysis using the Fourier transform infrared spectroscopy (FTIR), the thermo gravimetric analysis (TGA), the scanning electron microscopy (SEM) and the differential scanning calorimetry (DSC). The untreated biomass was subjected to biochemical methane potential (BMP) tests to optimise and predict the biogas potential for the selected biomass. A preliminary run was carried out with the agricultural biomass to determine which of the WW streams would yield the most biogas. Among the four WW streams sourced at this stage, two WW streams; sugar WW (SWW) and dairy WW (DWW) produced the highest volume of biogas in the increasing order; SWW ˃ DWW ˃ brewery WW > municipal WW. Therefore, both SWW and DWW were selected for further process optimisation with each biomass. Using the response surface methodology (RSM), the factors considered were temperature (25-55 °C) and organic loading rate (0.5-1.5 gVS/100mL); and the response was the biogas yield (m3 /kgVS). Maximum biogas yield and methane (CH4) content were found to be 5.0 m3 /kgVS and 79%, respectively, for the AcoD of CS with SWW. This established the association that existed among the set temperatures of the digestion process and the corresponding organic loading rate (OLR) of the AcoD process operating in batch mode. Both CS and SCB have been classified as lignocellulosic and thus, ionic liquid (IL) pretreatment was adapted in this study to ascertain their potential on the biogas yield. Results showed that the maximum biogas yield and CH4 content were found to be 3.9 m3 /kgVS and 87%, respectively, after IL pretreatment using 1-ethyl-3-methylimidazolium acetate ([Emim][OAc]) for CS with DWW at 55°C and 1.0 gVS/100mL. The IL pretreatment yielded lower biogas but of higher purity of CH4 than the untreated biomass. Data obtained from the BMP tests for the untreated and pretreated biomasses were tested with the existing kinetic models; first order, dual pooled first order, Chen and Hashimoto and the modified Gompertz. The results showed that for both untreated and pretreated biomass, the modified Gompertz had the best fit amongst the four models tested with coefficient of correlation, R 2 values of 0.997 and 0.979, respectively. Comparatively, the modified Gompertz model could be the preferred model for the study of industrial WW when used as co-substrate during AcoD for biogas production. The study showed that higher biogas production and CH4 contents were observed when CS was employed as a reliable feedstock with maximum volume of the untreated and pretreated feedstock reported at 31 L and 20 L respectively.
Anaerobic co-digestion with industrial wastewater for biomethane production
(2020-10-20) Adedeji, Jeremiah; Chetty, Maggie
The increasing demand for energy has led to the utilization of fossil fuels more abundantly as a quick alternative for generation of energy. The use of these sources of energy however as led to the generation of greenhouse gases which tend to cause climate change, thus affecting the ecosystem at large. Thus, there have been the search for alternative sources which cannot be depleted but do generate minimal greenhouse gases. One of such alternate sources is industrial wastewater which have shown to have high concentration of nutrients in the form of organic contents which can be converted by micro-organisms into energy, usually known as biogas, comprising majorly of CH4, CO2 and H2. Another important factor is that industrial wastewaters are a renewable energy source which are continuously generated due to increasing urbanisation and population growth. In this study, the characteristics of three agro-industrial based wastewaters used shows their potential for application in anaerobic co-digestion”. Anaerobic co-digestion method was utilized to harness the synergetic effect of both sewage sludge and agro-industrial wastewater as co-substrate for the generation of biomethane. The result of the effect of varying mix-ratio of the substrates on biomethane production of sugar wastewater and dairy wastewater indicated that mix-ratio of 1:1 for sewage sludge to sugar wastewater operated at 35oC was suitable for optimum generation of biomethane of 1400.99 mL CH4/g COD added and COD reduction of 54%. The model generated using design expert was found to navigate the design space and could perfectly predict the yield of biomethane effectively for the sugar wastewater mix. The biomethane potential tests (BMP) experiment using varying inoculum-substrate ratio (ISR) showed that operating at mesophilic temperature of 25oC with ISR of 1:2 and 2:1 for sugar wastewater and dairy wastewater respectively does increase the methane production within the first three (3) weeks. The kinetic models that best fit the anaerobic co-digestion for sugar wastewater was the first order model while the simplified Gompertz model favoured the dairy wastewater perfectly. The biomethane potential tests indicate significant increase the biomethane production and as well reduction in the volatile solid and chemical oxygen demand (COD) content. In conclusion, both sugar and dairy wastewater can be recommended as co-substrates for anaerobic digestion of sewage sludge for increased and improved biomethane production while simultaneously reducing their COD content at the same time.
Application of kaolin-based synthesized zeolite membrane systems in water desalination
(2021-12-01) Aliyu, Usman Mohammed; Isa, Yusuf Makarfi; Rathilal, Sudesh
Accessibility to potable water worldwide is threatene, despite 71% of the earth’s surface being covered with water. However, 97% of the 71% is too saline for consumption. A usual way of treating salinity is by membrane desalination using reverse osmosis. The disadvantage of this approach is its high cost and short life span of the polymeric membrane used. Creating a new robust high-quality water treatment system using a ceramic membrane will address these challenges due to its robust mechanical properties. In this work, we synthesized different zeolites from South African kaolin under varying conditions such as crystallization time, ageing time and temperature and their effects on the properties of zeolites synthesized was investigated. Sample characterization confirmed the successful synthesis of ZSM-5 and zeolite A. In the synthesis procedure, metakaolin served as the alternative source of silica and alumina and was use to synthesize different types of zeolites under varying synthesis conditions. Synthesized samples were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy and Brunauer–Emmett–Teller BET surface area. The properties of the synthesized ZSM-5 were influence by the synthesis parameters, typically, crystallization temperature, ageing time and crystallization time. Crystalline ZSM-5 zeolite produced at an ageing time of 24 hours, crystallization time of 48 hours and crystallization temperature of 180°C with Si/Al ratio of 43 and BET surface area of 282 m2 /g. After a 12-hour ageing period, Zeolite A produced at crystallization time of 20 hours, the crystallization temperature of 100°C, Si/Al ratio of 1.3 and BET surface area of 143.88 m2 /g. The findings indicate that aging influences the synthesis of zeolite A, as a relatively crystalline material formed at an ageing time of 12 hours, which continued to decrease as the ageing time was increased. We do not exclude the possibility of Ostwald ripening playing a role in this relationship. Subsequently, the efficiency of zeolite A and ZSM-5 zeolite in removing salt ions, Ca2+, K+ , Mg2+ , and Na+ from synthetic seawater was investigated at room temperature using a batch adsorption system. The effect of adsorbent dosage, agitation speed and contact time were consider. Dosages varied from 2.5 to 6.0 g/100 ml while the contact time varied from 30 to 180 minutes. The results obtained showed that a zeolite dosage of 6.0g/100 ml and agitation speed of 140 revolutions per minute (rpm) yielded a maximum removal efficiency of 89.7 % for Ca2+ and minimum removal efficiency of 1.8 % for Mg2+ at agitation rates of 30 and 120 minutes, respectively. Ion exchange of Na+ by Ca2+, K+ and Mg2+ in the zeolite framework was established. The preference of the overall ion-exchange selectivity of both zeolites A and ZSM-5 are in the order of Ca2+ > K+ > Na+ > Mg2+. Zeolite A showed higher removal efficiency compared to ZSM-5 zeolite. The results point out that the synthesized zeolite was able to desalinate the salt ions in synthetic seawater to a limit below the World Health Organization (WHO) recommended values. Consequently, zeolite synthesized from kaolin offers a cost-effective technology for the desalination of seawater. The desalination and material characterization results used in selecting a potential zeolite for use in reverse osmosis (RO). The material successfully deposited on etched alpha-alumina support to produce zeolite membrane by a hydrothermal technique using a modified in-situ method. Zeolite A and ZSM-5 membranes produced and applied in the RO unit for desalination. The RO membrane experimental results show potential in desalination of synthetic seawater. A machine-learning tool was use to predict the properties of the synthesized ZSM-5 as a function of the hydrothermal parameters. Finally, a techno-economic analysis of synthesizing zeolite using locally available kaolin at a capacity of 5 x 105 kg/yr. has shown that the plant is economically viable with rapid break-even and the payback period is less than 4 years.
Application of synthesized magnetic nanoparticles for biogas production using anaerobic digestion
(2023) Amo-Duodu, Gloria; Rathilal, Sudesh; Chollom, Martha Noro
South Africa is encountering severe challenges in the areas of energy, water, and wastewater management in recent times. This study addresses both water and energy aspects. It aims at using synthesised magnetic nanoparticles (MNPs) on anaerobic digestion (AD) for biogas production from various wastewater sources in South Africa. The study experimented the feasibility of five different synthesized magnetic nanoparticles, magnetite (Fe3O4), copper ferrite (CuFe2O4), nickel ferrite (NiFe2O4), magnesium ferrite (MgFe2O4) and aluminium ferrite (AlFe2O4) on two different wastewater samples (industrial and municipal wastewater) from three sampling sources, Umbilo water works, Umgeni water and a sugar refinery industry. Five research objectives were accessed. The first objective was the synthesis and characterisation of MNPs using scanning electron microscopy/energy dispersive x-ray (SEM/EDX), Brunauer-Emmett-Teller (BET), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) analysis. The results showed a surface morphology of facecentred and monoclinic crystal structures with a size less than 20 nm. The nanostructures of ferrimagnetite and magnetite were obtained, and it had an O-H stretching and Fe-O vibration functional groups. The surface area obtained was found to be high for magnetite (Fe3O4) which was 27.597 m2 /g. The second objective was to evaluate the AD performance in terms of water quality and biogas production. This was carried out in two stages. The first was to evaluate the five MNPs with sugar refining wastewater. The second stage was to evaluate the performance of three best performing MNPs on two wastewater samples from Umbilo wastewater. The results for the first stage showed good degradation of organic matter for the bioreactors with MNPs which resulted in a higher yield of biogas and methane as compared to the control as well as good removal of contaminant (chemical oxygen demand (COD), colour and turbidity). Among the five MNPs used, Fe3O4, NiFe2O4 and CuFe2O4 had a contaminant removal efficiency of 60- 70% and a cumulative biogas yield of more than 140 ml/day with more than 85% methane composition, hence these three MNPs were found to be the best performed MNPs. The results obtained from the second stage for the three best performed MNPs indicated a high pollutant removal efficiency of more than 70% for Fe3O4, as well as a biogas yield of more than 1100 ml/day and a methane composition of approximately 98%. The third objective was the evaluation and optimisation of the anaerobic magnetised system for biogas production while the fourth objective involved a comparative study between the performances of magnetised biochemical methane potential (BMP) to non-magnetised biochemical methane potential. From the optimisation study, the predicted results obtained from the BBD-RSM showed an average contaminant removal of 70% and a biogas yield of 522 ml/day at an optimum MNP load of 0.5 g, retention time of 45 days, inoculum load of 500 ml, and a temperature of 35℃ with a desirability of 96% as the optimum conditions. With less than 2% deviation, the confirmatory test demonstrated equal performance at the optimum conditions. Findings from the fourth objective indicated that the BMP system with MF exposure exhibited a contaminant removal rate of over 80% and a biogas generation of 1715 ml/day with a 99.94% methane composition. Overall, the system that included both MF and MNP performed better than the other in terms of biogas yield and colour removal. The final objective was the kinetic study of the anaerobic magnetised system using modified Gompertz and first-order kinetic models. The results obtained from the kinetics showed that the modified Gompertz model described the kinetics and dynamics of the anaerobic magnetised system better than the firstorder kinetic model with a correlation co-efficient (R2 ) over 0.9999 and an error less than 0.0002. Therefore, the possibility of using MNPs, particularly magnetite (Fe3O4), in an AD system for biogas production from wastewater was found to be extremely feasible and without negative environmental consequences. Incorporating both MF and MNP in AD was also beneficial for wastewater treatment because it eliminated the need for post-treatment.
Artificial intelligence based solar/diesel hybrid water pumping system
(2021-12-01) Moyo, Ranganai Tawanda; Tabakov, Pavel Y.
Solar energy powered systems are increasingly being implemented in different areas due to the advances in solar energy technologies. Some of the major areas for solar energy applications include solar water heating, solar electric power generation, and solar water pumping. Solar water pumping has become the most adopted solar energy technology in the last decade. It has been considered as an attractive way to provide water in remote areas. A major advantage of using solar water pumps is that they are naturally matched with solar irradiation since usually water demand is high in summer when solar irradiation has its maximum values. However, solar energy powered systems are weather dependent. In most cases, a solar energy source has to be combined with another energy source to form a hybrid system to overcome the demerits of using solar alone. This thesis provides the detailed design, modelling and analysis of an Artificial Intelligence (AI) based solar/diesel hybrid water pumping system. This research aims to develop an optimization model that uses AI techniques to maximize the solar energy output and manage the energy flow within the solar/diesel hybrid water pumping. Thus, the proposed system is composed of solar photovoltaic modules, battery bank, Variable Speed Diesel Generator (VSDG), Adaptive Neuro-Fuzzy Inference System (ANFIS) based Maximum Power Point Tracking (MPPT) controllers and an Energy Management Controller (EMC). The EMC, which is based on Fuzzy Logic (FL), is responsible for managing the flow of energy throughout the hybrid system to ensure an undisturbed power supply to the water pump. The PV array, battery bank, VSDG are all sized to power a 5Hp DC water pump and the ANFIS based MPPT controllers are proposed for improving the efficiency of PV modules. The modelling of the system components is performed in the MATLAB/Simulink environment. For evaluation of the proposed system, several case scenarios were considered and simulated in the MATLAB/Simulink environment. The simulation results revealed the effectiveness of the proposed ANFIS based MPPT controllers since the controllers were able to extract maximum available power from PV modules for both steady-state and varying weather conditions. The proposed EMC demonstrated the successful management and control of the energy flow within the hybrid system with less dependency on the VSDG. The EMC was also able to regulate the charging and discharging of the battery bank.
Assessing the feasibility and effectiveness of rooftop rainwater harvesting in Winnie Mandela Madikizela Local Municipality
(2023-05) Nakin, Abongile Ongezwa; Walker, Mark; Ikegwuoha, DC
South Africa's primary source of water is surface water. The potability of this water is doubtful especially in rural areas. Evaluation of rainwater quality from various roof materials is crucial. Additionally, there is a need to evaluate the quantity and the economic viability of Rooftop Rainwater Harvesting (RRWH). Winnie Madikizela Mandela Local Municipality (WMMLM) of Nomlacu currently has 73.6% municipal water supply backlog. With the current challenges, it is important not only to explore ways to save water but also to generate own sources of water. This makes RRWH systems as a viable water resource, an option for alleviating water scarcity. The study aims to assess the feasibility and effectiveness of RRWH for domestic use in WMMLM. The target is to determine the potential of rainwater harvesting as a potable water supply and conservation alternative. Hydrological data was obtained from the Weather SA to facilitate the calculation of the quantity of rainwater that can be harvested per household. Moreover, catchment areas were obtained through QGIS to determine size and materials of the roof types. Thus, to analyse the impact of roof materials on water quality for human consumption and irrigation. According to the results obtained in this study, Turbidity and E. coli produced noncompliant results of (0.8 – 2.8 NTU) and (0 - >2420 MPN /100mL) respectively. Although within limits, Aluminium, Colour, and Zinc concentrations present higher values on zinc metal roof compared to tiled roofing material. This is due to the high radiation and good heat conducting capacity of the metal. Results also showed higher pH levels on tiled roofs (7.05 – 7.39) compared to zinc roofs (6.27 – 7.19), which is in line with the nature of concrete. The most significant and immediate threat to health that roof collected water poses is bacterial contamination. Therefore, it is important to regularly clean the system, use disinfection solutions like chlorine tablets and boiling water before consumption. Overall, Nomlacu area receives relatively high amounts of rainfall which is greater than country’s annual rainfall. The study showed that RRWH can meet the annual demand of rainwater and have an overflow of roughly 7211L/year which is equivalent to an approximate potential annual harvest of 124% when utilized to its optimal potential and at worst case scenario can alleviate the pressure from the municipal water supply system by at least 81%. Results showed that optimal rainwater harvesting can be achieved by using more than two storage tanks per household. This then makes it possible for the system to alleviate pressure from the municipal water supply. On the economically aspect, installing a RRWH system is financially feasible, it would spare the municipalities approximately 48.8% of the municipal water supply spend to supply water to the municipality should this project be a government initiative.
An assessment of the adoption of smart building concept in the Nigerian construction industry
(2022-05-13) Ejidike, Cyril Chinonso; Mewomo, M. C.
Technological penetration across developing countries has impacted the construction industry, with more construction stakeholders deploying various technologies into the building lifecycle's design, construction, management, and maintenance. The building sector has evolved by adopting and implementing smart tools for its operations over the past few years. Building information modelling (BIM), the internet of things (IoT), and smart devices (sensors) are game-changers that have helped to reduce the complexity of construction activity and increase productivity. Meanwhile, introducing the sustainable development concept in the construction industry has enabled the proper management of the earth's natural resources and provided a pathway for ecosystem balance alongside socio-economic development. Amid the skyrocketing population growth, urban sprawl, and globalization, the building industry is confronted with the challenge of providing adequate and holistic built infrastructures such as efficient energy management, good water supply, occupants' indoor comfort, and the management of construction waste. The smart building concept (SBCs), which employs sustainable construction whereby the built product is constructed according to best practices, including efficient energy use, the recycling of raw material, and the realization of a sustainable and carbon-free environment, has demonstrated the digitalization of sustainable development in the construction industry. Therefore, this dissertation seeks to asseeement of the adoption of smart building concepts in the Nigerian construction industry. The research poses the following questions: 1) What is the awareness level of construction professionals in the adoption of the smart building concept (SBCs) in the Nigerian construction industry? 2) What factors can enhance the awareness of the smart building concept among construction professionals in the Nigerian construction industry? 3) What factors enhance the adoption of SBCs among professionals in the Nigerian construction industry? 4) What are barriers to adopting SBCs in construction projects in the Nigerian construction industry? A random sampling technique in selecting the construction professionals. The total population of construction professionals within the study area is 5,108, comprising construction professionals of Architects, Builders (Mechanical, Electrical, and Structural), Engineers, and Quantity Surveyors practicing in Lagos state. The sample size selection was made using the Yamane formula (1967) for calculating sample size. Therefore, the sample for this study is 363. A well-structured questionnaire of 363 was administered to construction professionals to gather relevant data on the topic. The data collected were analyzed using the Kruskal Wallis H test and weighted mean, factor analysis, and binary regression analysis, and mean item score and agreement analysis technique. The key finding of the research indicated that construction professionals are generally aware of the smart building concept. Administration, education, organizational, and environmental factors were discovered to enhance the adoption of smart building concepts among construction professionals. Furthermore, the research indicates that energy and cost-saving, job creation, safety and security, and health care are the critical factors enhancing in adoption of smart building concepts among construction professionals in the Nigerian construction industry. Lastly, the research result discovered that the high cost of smart building materials, inadequate power supply, resistance to change from the use of traditional technology, poor maintenance culture, poor knowledge of smart building technology, inadequate well-trained labour in the practice of smart building construction, and inadequate finance schemes are the significant barriers to the adoption of smart building concept. Based on this research finding, the research recommends that construction professionals engage more in smart building concepts, propagating the country's awareness and development of smart building construction. Furthermore, the government should establish a common platform for the collaboration of all stakeholders, such as professionals in the construction industry and academia, by way of policymaking and funding of research and development towards implementing these smart technologies. It will go a long way for employment creation and improve the country's economy. This study contributes to the body of knowledge by discovering the critical factors that will aid the successful adoption of the smart building concept in the Nigerian construction industry.
Basic mathematical modelling for polymer woven fabric performance suitable for low energy filtration systems
(2019) Mncube, Blessing Thokozani; Rathilal, Sudesh; Pillay, Visvanathan Lingamurti
Water is one of the most important and essential resources that people usually misuse and take for granted until it is either gone or unsuitable to be utilized for domestic, industrial or agricultural purposes. The need to explore affordable purification technologies is essential. The filtration processes are innovative technologies that can be employed in water treatment systems or water purification technologies. However, the filtration technologies have one prime limitation factor of which is fouling and biofilm formed on the membrane surface sometimes internal. Recent advancements in polymer science and textiles have led to developing fabric material that can be used as membranes suitable for emerging economies. For years’ people do use fabric to purify river water especially women from rural areas. Yet non-woven materials are used as a membrane by industries as compared to woven fabrics. However, most non-woven fabrics are easily damaged when cleaned with a polymer brush and require periodical replacement. The tapeline and filter manufacture use a woven fabric as a backer before casting or putting a filter on the weave fabric. These prove the fact that any woven fabric can be modified for optimal use. On the other hand, most Engineers and scientists have not given much attention to woven fabrics as a result, woven fabrics are not employed as membranes. Some scientists and engineers believe that woven fabrics are not suitable for treating water for domestic use. Some believe that some woven fabrics can be used as membranes provided they are capable to remove unwanted materials like bacteria and pathogen. The aim of this study is to create a full understanding of the factors that affect the fabrics when used as membranes, especially when the polymer woven fabrics are used as filters to treat water and wastewater. It is essentially important to develop standardized procedures or models that accurately describe the textile woven fabrics behaviour when used as filters. The standardized models or procedures will assist engineers and scientists when developing filtration systems using woven fabrics. The first objective was to evaluate and compare the fabric types that can be used as filters or membranes in water and wastewater treatment processes. The second objective was to identify the applications for woven fabric membranes and evaluate the factors that play a critical role during the filtration process and relationship between those factors. The experimental investigations conducted were to evaluate the (1) main objectives; (2) effect of membrane orientation; (3) effect of feed quality on membrane performance; (4) effect on stable flux quality and quantity of the selected fabrics; (5) effect of fabric type on filtration or microfiltration processes; (6) effect of membrane fouling on membrane performance; (7) develop the basic model suitable in identifying the right fabric for any filtration system operating at low energy. The experimental investigations conducted were to evaluate the selected woven fabrics that were manufactured in South Africa, easy to clean with a polymer brush. Those woven fabrics were tested using South African river water and wastewater from treatment plants. When evaluating different feed solutions, bio-fouling was considered to be the major limiting factor of woven fabrics, but the feed with a lot of bio impurities can be modified for optimization processes. Laboratory apparatus and field apparatus was developed to analyze and evaluate the effect and behaviour of fabrics performance, and cake formed on the fabrics. The result clearly states that a solution or wastewater with a lot of biological organisms produce lower flux and also produces a lower critical/stable flux when compared with the solution with more incompressible solids or impurities. The result clearly shows that all selected fabrics can be used as filters however; the polyester fabric was the only fabric that can be used for microfiltration processes suitable to clean water for domestic use. This polyester fabric removes 99.995% of impurities from the polluted waters. The Permeate water quality coming from this polyester fabric was less than 1NTU, before and after stable flux. Other fabrics can be used as filters but not for microfiltration. These three fabrics are not capable of removing micro-impurities (less than 20 micrometres). The basic mathematical modelling Equation developed, proved that the membrane pore size, driving force, impurities size in polluted water, impurities nature and impurities concentration play major roles in the filtration process especially in stable flux formation. The simple Equation F = Ae−Bt + C was discovered to be suitable to evaluate the fabric performance, where C is the constant flux value, A is the maximum flux value and B is the part of the critical area or rate change. The Equation can be applied to most fabrics that are used as filters. Testing the maximum flux value was critical and achievable when using pure and clean water especially the distilled water. The results show that most solutions with high compressible impurities will take less time to reach a critical or stable flux. The solution or effluent or river water with more bio impurities and more bacteria will have less flux when compared with a solution with more incompressible impurities. Most polymer woven fabrics do not require any sophisticated technologies or additional chemicals to clean. It can be easily brushed with a polymer brush. Brushing the surface of the fabric with balanced tensile strengths in both warp and weft yarns will not rearrange, damage, or affect the pore size. Only sharp objects can damage the polymer fabrics. The knowledge of this report will assist in optimising the filtration system operation at low energy when using woven polymer fabrics as membranes for filtration. The basic mathematical model can be useful to engineers and scientists willing to use woven fabrics as membranes. Hence, mathematical modelling is one of the important tools of engineering optimization and design. This study focuses on the low energy (gravity-driven) systems that treat water and wastewater like Household Point of Use (POU) systems. Other POU systems were tested and compared to POU systems that are made of the Polymer woven fabric. Based on results, it can be concluded that POU's that uses polyester membranes (PWF-POU) are good prospects for area without sophisticated water or wastewater treatment systems since it removes almost all bacteria and impurities. Polyester woven fabrics can be used as a microfiltration membrane not only to process water or wastewater but also to process chemicals, oils, etc. The other selected fabrics that were made of polypropylene filaments need to be modification in order to operate at optimum when cleaning water for domestic and tertiary use. When modifying these polypropylene fabrics, the quality do improved.
Biological nutrient removal from industrial wastewater using a sequencing batch reactor
(2018) Khumalo, Siphesihle Mangena; Bakare, Babatunde F.
South Africa is not an exception when it comes to the issue of fresh water scarcity perpetuated by environmental pollution among many other factors. Industrial wastewater particularly emanating from the brewing industry, contains high-strength organic, inorganic, and biological compounds which are toxic to the environment. Due to stringent industrial effluent dewatering standards enforced by both local and international environmental protection entities, industrial wastewater cannot be discharged into receiving water bodies prior to treatment. The overall aim of this study was to evaluate the performance or treatment efficacy of a laboratory scale sequencing batch reactor on biological nutrient removal using industrial wastewater from brewery. In this study, two laboratory scale sequencing batch reactors (SBRs) operated in a cyclic aerobic-anaerobic configuration inoculated with activated sludge were investigated for their removal of orthophosphates and nitrogen compounds from brewery wastewater. SBR-1 was investigated for nitrogen group pollutant removal and SBR-2 was investigated for orthophosphate removal. The findings of the study are reported based on overall removal efficacies for the following process monitoring parameters: orthophosphates, ammoniacal nitrogen, total Kjeldahl nitrogen, total nitrogen, total organic nitrogen, total inorganic nitrogen and NO3-N+NO2-N. From the investigation, the following overall removal efficacies were obtained: 69% orthophosphates, 69% ammoniacal nitrogen, 59% total Kjeldahl nitrogen, 60% total nitrogen, 64% total organic nitrogen, 67% total inorganic nitrogen and 56% NO3-N+NO2-N at an organic loading rate of 3.17 kg Total Chemical Oxygen Demand (TCOD) /m3.day with a food to microorganism ratio of 2.86 g TCOD/g Volatile Suspended Solids (VSS).day. These removal efficacies were attained for a hydraulic retention time of 18 hours for both SBRs with a solids retention time of 5 days for SBR-1 and 7 days for SBR-2. Both reactors were operated at a mesophilic temperature range of 23 to 26˚C and a pH range of 5 to 8.5. The temperature was left unadjusted because it was observed that it did not hinder any microbial activities during the biodegradation process. The Michealis-Menten’s and Monod models were implemented to study the substrate utilisation rate kinetics and microbial growth rate kinetics recording 15 141 g COD/m3.day; 12 518 g VSS/g VSS.day; 20 343 g COD/m3.day and 16 860 g VSS/g VSS.day for SBR-1 and SBR-2, respectively. The Monod model demonstrated a strong correlation fit between the substrate utilisation rate and microbial growth rate recording a polynomial correlation constant of R2 = 0.947 and 0.9582 for SBR-1 and SBR-2, respectively. The findings of this study showed that the cyclic aerobic-anaerobic configuration on a laboratory scale SBR inoculated with activated sludge for treatment of brewery wastewater for biological nutrients was feasible.
Bioremediation of acid mine drainage and crude contaminated soils
(2020-09) Anekwe, Ifeanyi Michael; Isa, Yusuf Makarﬁ
Pollution is one of the greatest ills plaguing the existence of the ecosystem which could lead to the annihilation of terrestrial and aquatic habitat if not remedied. Acid mine drainage (AMD) and crude oil are among the major land and water pollutants cause by industrial and human activities. The constant exploration, mining, and processing of mineral resources and prevalent use of petroleum products for economic purposes have contributed to contamination of soil and proximate water bodies which results in environmental degradation; thus, remediation becomes necessary. The treatment of AMD contaminated soils using the conventional methods has some room for improvement to meet the remediation purpose. Bioremediation technology provides a sustainable and eco-friendly approach to the treatment of contaminants. This study aims to evaluate the performance of different potential bioremediation techniques and conduct a comparative analysis of these methods for the treatment of AMD and crude oil-contaminated soils. The treatment approach for both pollutants comprises of soils separately contaminated with AMD and crude oil before the application of bioremediation techniques. For the biostimulation study, contaminated soils were amended with varying ratios of the brewery or municipal wastewaters (BWW and MWW), while the bioventing (BVT) treatment involved wastewater amendment and supply of atmospheric air from the vadose zone at 3L/min at 30 minutes intervals every 48 hours. The bacteria strain Pseudomonas aeruginosa ATCC 15442 used for the study which was inoculated at 5%(w/w) was cultured in two different media for respective treatments and wastewater was amended as an extra energy source for bioaugmentation (BAU) study while Bioattenuation (BAT) which received no amendment was used as a control treatment for the study. The treatments were conducted in plastic bioreactors under mesophilic conditions for 28 days and samples were collected from each treatment system on weekly basis to analyse for sulfate, heavy metals, and total petroleum hydrocarbon (TPH) reduction. The result of the study showed that the amendment of contaminated soils with wastewater increased alkalinity in the system which enhanced microbial activities for effective remediation which recorded 52.43 and 51.23% average TPH and metal removal efficiency for the BSTc treatment. Also, the combined application of bioremediation techniques was more effective than single application as the introduction of oxygen into the treatment system with wastewater amendment increased the TPH and metal removal efficiency by an average of 12.98 and 13.17% respectively but efforts to enhance sulfate removal by air-injection (BVTa) proved abortive with 17.20 and 14.67% removal efficiencies less than BSTa and BAUa respectively as sulfate-reducing bacteria thrive in an anaerobic environment. However, P. aeruginosa ATCC 15442 adopts the sorption process in the reduction of hydrocarbon and metal toxicity with 42.02 and 41.81% average removal efficiencies respectively and the amendment extra nutrient (wastewater) increased the removal efficiency of these pollutants by 25.24 and 16.23% respectively. The results of the study inferred that wastewater (BWW and MWW), air-injection and P. aeruginosa ATCC 15442 showed great potentials in the degradation and removal of TPH, metals and sulfate contaminants, hence, can serve as a viable strategy for the remediation of AMD and crude oil polluted soils while improving waste management and amelioration of pollution aftermath faced by communities involved in mining and oil production and/or processing. There is a need for optimization to ensure effective remediation while further study is required to validate large scale application.
The biosorption of chromium and copper from AMD contaminated water using banana peels as a biomass adsorbent
(2022-09-29) Mzimela, S'thembile; Musonge, Paul; Bakare, Babatunde F.
The presence of heavy metals in water from industrial activities negatively affects human health. Metal accumulation in human bodies is toxic and can lead to carcinogenic effects when consumed for prolonged periods. There is no acceptable method for permanently removing heavy metals in water. As a result, water for human consumption and domestic use from various water sites contains harmful heavy metals. This study investigates the removal of hexavalent chromium (Cr6+) and copper (Cu 2+) from drinking water through the adsorption process using banana peels as biomass material. Banana peels were evaluated for their ability to remove heavy metals from water as a cheaper alternative resource to conventional adsorbents such as activated carbon. Cr6+ and Cu2+ are some of the most common heavy metals found in potable (drinking) water and they were chosen for this study amongst other heavy metals. Batch studies were conducted using water that was synthesized with the chosen metals. Parameters such as pH, agitation speed, biosorbent dose, initial metal concentration, and contact time were varied to determine their effect on biosorption. pH was varied between 2 and 7, agitation speed was varied between 100 and 200 rpm, dosage was varied between 1 and 6 grams, initial concentration was between 5 and 100 mg/L and contact time was also varied between 5 and 140 minutes. Each variable was done one factor at a time while keeping other values constant. The height of the column for column studies was studied between 5 and 30 cm at constant pH “4”, 5mg/L initial metal concentration and volumetric flowrate of 4mL/min. Results from the study showed that pH for both Cr6+ and Cu2+ was highest at pH “4” with % removal of 65% and 94%, respectively. Agitation speed had a high % removal at 180 rpm for Cr6+ (67%) and 160 and 180 rpm for Cu2+ (95%). Increase in biosorbent dose also increased biosorption efficiency from 17% to 95% for Cu2+ across the range, and from 58% to 65% for removing Cr6+ . In the study of initial metal concentration, banana peels performed better at lower metal concentrations for both metals. Highest % removal efficiency for Cr6+ was found at 5 mg/L at 64% and for Cu2+ at 10, 15 and 20 mg/L at 95%. Contact time between 5 and 140 minutes found that equilibrium was reached within 30 minutes for Cr6+ and within 50 minutes for Cu2+ . Adsorption equilibrium isotherms and kinetics were studied for both metals and found that the biosorption of Cr6+ followed the Freundlich isotherm and Langmuir isotherm models with R 2 of 0.99 and 0.95 respectively, and the process kinetics followed the pseudo-second-order kinetic reaction with R 2 of ~ 1. The biosorption of Cu2+ followed the Langmuir isotherm model with R 2 of 0.96 and Langmuir qm of 15.41 mg/g and the process kinetics followed the pseudo-first-order kinetic reaction as well as the intra-particle diffusion model with both R 2 of 0.98. Banana peels were characterized for their properties and the Fourier transform infrared (FTIR) spectroscopy identified the functional groups in the peels which were hydroxyls, carboxylic acids, alkanes, and amines. Most of the groups were active in the removal of Cr6+ and Cu2+. The scanning electron microscopy (SEM) identified the surface of the peels to be rough with uneven areas and the energy-dispersive x-ray spectroscopy (EDS) analysis identified the elements present in the peels which were carbon (C), oxygen (O), potassium (K), chloride (Cl) and silicon (Si). The x-ray diffraction (XRD) was used to identify the phase of the peels and it was found that the peels were amorphous with some crystallinity containing a crystal salt called sylvite. The Brunauer–Emmett–Teller (BET) analysis identified the pores of the banana peels to be mesoporous with a pore size of 2.9 nm, a surface area of 5.69 m2 /g, and a pore volume of 0.002605 cm3 /g. Column experiments in a fixed-bed column were studied for the removal of Cr6+ and the breakthrough time tb increased from 10 min at 5cm to 420 min at 30 cm. The mass transfer zone HB also increased from 0.206 at 5 cm to 7.426 at 30 cm. Other column performance indicators such as the adsorbent exhaustion rate (AER) and the number of volumes processed (NBV) showed that biosorption was efficient and dependent on bed height for better performance. The process favoured the Adams-Bohart model with R2 ranging between 0.94 to 0.98 and the Yoon-Nelson model with R2 ranging between 0.93 and 0.97. It can be concluded from this study that banana peels have the ability of removing Cu and Cr in potable water and has provided some insight for scaling-up of adsorption columns.
Biosorption of Fe2+ from potable water using natural and modified sugarcane bagasse
(2023-05) Ndebele, Nompumelelo Lindi Gelsiah
Even though some metals are crucial for the health and development of human bodies, their presence in higher concentrations is worrisome because it has a detrimental effect on people's health. These heavy metals cause cancer and cannot be broken down by biological processes. The removal of heavy metals from water using traditional techniques; such as reverse osmosis, precipitation, ion exchange; has been the subject of extensive investigation. However, because these processes are so expensive to run, a lot of research is currently focusing on using agricultural biomasses to remove these heavy metals. Dumping of this agricultural waste (sugarcane bagasse) in landfills creates dangers of spontaneous combustion, because of microbial activities. The functionality of circular economy depends on waste resources being utilized to their fullest potential, with almost no production of recoverable waste. In a circular economy, sugarcane bagasse is utilized as a fuel source for the boilers that generate process steam and electricity in the sugar mill facilities. Sugarcane bagasse is used in the manufacturing of paper and paper goods, as well as in the agricultural sector. Stakeholders across the value chain, from product design to waste management, This study fulfils the functionality of the circular economy where it looks at extracting the valuable components of the sugarcane bagasse, then further using the sugarcane bagasse to remove heavy metals from potable water. In this study, the adsorption capacities of unmodified and modified sugarcane bagasse for removing Fe2+ from potable water were investigated in batch experiment studies. Sugarcane bagasse comprises cellulose, hemicellulose and lignin. In order to determine the effect of removing/ extracting each component from the sugarcane bagasse, sugarcane bagasse was pretreated with different concentrations of sodium hydroxide and sulphuric acid, ranging between 0.5 wt% and 2.5 wt%, predominantly used to extract lignin and hemicellulose. A cellulosic structure was left behind after the simultaneous removal of both amorphous components (the lignin and the hemicellulose) using the combined pretreatments of sodium hydroxide and sulfuric acid. The advantages of extracting or eliminating these components came from their high value in many sectors. Lignin is used in the paper business and costs between R11 300 and R17 420 per ton, hemicellulose is used in the pharmaceutical sector and costs between R500 and R1000 per ton, and cellulose is utilized in the textile sector. The concentrations of all chemical pretreatments used on the sugarcane bagasse ranged from 0.5 to 2.5%, with alkaline pretreatments intended to extract lignin, acid pretreatments intended to extract hemicellulose, and combination pretreatments intended to remove both lignin and hemicellulose. While cellulose content increased from 32.02 to 65.65% after sodium hydroxide pretreatment, lignin and hemicellulose content reduced from 22.30 and 24.30% to 7.56% and 13.63%, respectively. Lignin and hemicellulose concentration for the sulphuric acid pretreatment went from 22.30 and 24.30% to 14.90% and 13.63%, respectively, while cellulose content went from 35.02 to 65.65%. After the sugarcane bagasse underwent chemical pretreatments, batch studies were conducted on both the natural and chemically pretreated sugarcane bagasse in order to determine how the removal of lignin, hemicellulose, and cellulose affected the performance of the biosorbents in the biosorption of Fe2+ from drinkable water. To assess the efficacy of natural and modified sugarcane bagasse on the Fe2+ removal, the operational parameters investigated in the batch experiments were initial concentration ranging from 1 to 30 mg/L; pH ranging from 2 to 7, contact time ranging from 5 -100 minutes, and adsorbent dose ranging from 0.2 to 1.4 g. For every variation investigation, one variable was varied at a time while keeping the other variables constant. The experimental runs done were repeated thrice and average values are reported throughout the study. According to the biosorption results, 1% NaOH was the best performing biosorbent for the alkali-pretreatment. The most effective biosorbent for the acidpretreatment variation was 2.5% H2SO4. The optimal combination for the pretreatment was (0.5% NaOH + 0.5% H2SO4). Regarding initial concentration variations, all biosorbents were most effective at a concentration of 1 mg/L, where natural sugarcane bagasse was able to remove 50% of Fe2+, 1% NaOH was able to remove 99.7% Fe2+, 2.5% H2SO4 removed 75.93% Fe2+, and the combined-pretreated biosorbent of (0.5% NaOH + 0.5% H2SO4) removed 87.17% Fe2+ . The increase in biosorbent dose led to an increase efficiency of the natural and chemically pretreated biosorbents. The highest removal of Fe2+ was obtained at 1 g (both for the natural and for all the pretreated biosorbents), with 32.2% for the natural; 79.04% for the 1% NaOH; 58.79% for the 2.5% H2SO4 and 70.73% for (0.5% NaOH + 0.5% H2SO4). Results of the study also showed that the highest removal of Fe2+ for the pH variation of 2-7 was at pH “6” for both the natural and pretreated biosorbents. For the variation of the agitation speed, the highest Fe2+ removal was at 160 rpm with 52% Fe2+ removal for the natural sugarcane bagasse. The Langmuir and Freundlich adsorption isotherms were used to study the biosorption mechanisms. Good correlation coefficients (R 2 ) of > 0.95 were obtained for both the Langmuir and Freundlich isotherms for both the natural and modified sugarcane bagasse, indicating that the biosorption followed both homogeneous and heterogeneity interaction between Fe2+ ions and active functional groups of the surface and pores of the biosorbents. Biosorption results for the natural sugarcane bagasse best fitted with the Langmuir isotherm with qmax of 0.770 mg/g, R 2 of 0.987 and RL of 0.938. The alkali and acid-pretreated biosorbents favoured both the Langmuir and Freundlich isotherms with R 2 > 0.95; RL < 1 and 1 𝑛 < 1. The highest qmax of 9.199 and 5.743 mg/g was obtained at 1% NaOH and 2.5% H2SO4, respectively. The combined pretreatment fitted best with only the Langmuir isotherm with R 2 of 0.987, the R 2 of the Freundlich isotherm was less than 0.9. The biosorption of Fe2+ followed both the pseudo-first-order and pseudo-second-order kinetic reactions with 𝑞𝑒(𝑒𝑥𝑝) in close proximity to 𝑞𝑒(𝑐𝑎𝑙𝑐) and R 2 > 0.9. These results showed that sugarcane bagasse had great adsorption capacity after removing the valued components, namely, lignin and hemicellulose. Characterization studies, which included FTIR, XRD, BET and SEM, were also carried out on the natural and pretreated bagasse before and after adsorption experiments. FTIR confirmed the existence of carbonyl, hydroxyl and carboxyl functional groups as major groups responsible for the adsorption of Fe2+ onto the natural and pretreated sugarcane bagasse. XRD revealed that the natural structure of the sugarcane bagasse was of native cellulose consisting of both amorphous and crystalline regions; this structure became more crystalline after the chemical pretreatments as the crystallinity index increased from 39.04% to 66.85% at 1% NaOH; 57.47% at 2.5% H2SO4; and 57.92% at (0.5% NaOH + 0.5%H2SO4). The natural sugarcane bagasse structure featured rough surfaces, according to SEM data, and the main constituents were silicon (Si), carbon (C), and oxygen (O). According to the BET data, employing 1% NaOH, 2.5% H2SO4, and (0.5% NaOH + 0.5% H2SO4), respectively, the initial surface area of 0.904 cm3 /g rose to 1.503, 1.233, and 1.376 cm3 /g and the pore size of 56.33 ̊A increased to 99.63, 93.680, and 99.10 ̊A. According to the EDS data, sodium hydroxide pretreatment performed better in terms of adsorption, followed by combined pretreatment and sulphuric acid. The natural sugarcane bagasse, 1% NaOH, 2.5% H2SO4, and (0.5% NaOH + 0.5% H2SO4) were able to biosorb 0.77, 7.89, 1.63, and 3.8% Fe2+, respectively.
Characterisation of concrete with expanded polystyrene, eggshell powder and non-potable water : a case study
(2023-05) Mncwango, Bonke; Allopi, Dhiren
Urbanisation has brought many benefits but it has also highlighted the global lack of housing alongside global natural resource scarcity. Lack of housing on the surface appears to be a singular problem, however in reality it represents a number of society’s biggest challenges such as crime, pollution (as a result of inadequate waste disposal strategies), unhygienic living conditions, as well as numerous health problems. Governments across the world have made various attempts at addressing the issue of lack of housing, including embarking on large scale social and public housing initiatives, building smaller homes for the homeless, as well as removing certain regulatory barriers to allow more houses to be built at a reduced timeframe. These advances have assisted many individuals and families globally, however, there are still many individuals and families that government housing-aid or housing initiatives have not yet reached. These individuals and families are faced with solving their housing crisis on their own, with their own resources. Globally, concrete remains a supreme building material in the construction industry and therefore is a primary factor of consideration for solving the housing crisis, especially for those who have no financial assistance or aid from government. Concrete’s composition is simple: cement, fine aggregate, coarse aggregate and water. The intricate interaction between all four components is meant to stand the test of time. Unfortunately, it is not only the earth’s diminishing natural resource reserves which are causing a decline in the popularity of conventionally produced concrete, but it is also the irreparable harm that it is causing to the environment. The process of concrete production requires large volumes of cement, and cement remains one of the biggest producers of carbon dioxide. Carbon dioxide is a greenhouse gas which in excessive amounts creates a cover that traps the sun’s heat energy in the atmosphere. Another major criticism of conventional concrete is the requirement that it be produced with clean water which is of a drinkable standard. This criticism is justified when considering the extreme water shortages that are experienced by many low to middle income countries around the world. The amount of financial and human resources that local authorities invest in cleansing water to bring it to a drinkable standard is often overlooked. It is obvious that it is less expensive to use water directly from a river in its natural state than using it after it has undergone numerous cleansing processes by local authorities. There have been a notable number of advances in making concrete more resource-efficient and environmentally friendly. These include the advent of lightweight concretes such as expanded polystyrene concrete. Expanded polystyrene concrete not only saves the amount of aggregate that would normally be required in conventional concrete, it also has excellent acoustic and thermal properties, thereby reducing energy consumption which in turn saves money. However, even with such excellent properties, expanded polystyrene concrete still fails to address two of concrete’s major criticisms which are related to the amount of cement used as well as the amount of clean potable water required for mixing. Therefore, by building on the qualities of expanded polystyrene concrete, this research investigates the potential of lowering the amount of cement required in a concrete mix through the use of eggshell powder. Eggshells are a waste product found everywhere in the world and are readily available in almost limitless quantities. The use of eggshells in concrete to lower the amount of cement required will not only achieve a reduction in the amount of carbon dioxide that is produced in the process of producing concrete, it will also assist in contributing toward solving the escalating waste disposal crisis that currently exists for many waste types such as eggshells. It is common for communities to reside close to a river or a natural flowing watercourse, so this research included river water as a variable. Four different concrete mix scenarios were tested to ascertain through experimentation whether the strength properties of concrete that contains expanded polystyrene, eggshell powder and natural river water in various proportions could in any way compare to a conventionally produced concrete mix. In order to comprehensively study material behaviour in this case, sieve analysis, bulk density, fineness modulus, moisture content as well as specific gravity tests were performed on all aggregates used. Furthermore, in order to achieve the required analytical depth for the materials being studied, x-ray diffraction and energy dispersive spectroscopy tests were conducted. As a means of conducting further trend analysis on the different experimental mixes, logarithmic regression models were developed. Through analysis of the output attained from the aforementioned strategies, this research study found that when cement was substituted by eggshell powder at a percentage of 5 % and simultaneously when coarse aggregate was also substituted by expanded polystyrene at a percentage of 5 %, all mixed with non-potable water, the compressive and flexural strength outcomes marginally differed from the strength outcomes of conventionally produced concrete. Furthermore, the substitution of stone by EPS at a percentage of 10 % when mixed with river water was comparable to the substitution of stone by EPS at a percentage of 10 % when mixed with potable water. The results showed that there was a difference of not more than 1.4 MPa and 0.3 MPa in compressive and flexural strength respectively amongst the averages obtained at each age tested. Study results show that the substitution of potable water by non-potable water reduced both the compressive and flexural strength of the concrete when the mix did not contain eggshell powder. However, when eggshell powder was included in the mix, the strength outcomes of the compressive and flexural strength of the concrete mix was comparable to that of conventionally produced concrete. There may be many reasons why it is important to not deviate from convention in the production of numerous products such as concrete; nevertheless, the value of experimentation as demonstrated in this research is that experimentation can give rise to a variety of innovations accompanied by a wealth of solutions to the environmental and socio-economic issues that the world is currently faced with.
Chemical oxygen demand (COD) fractionation for process modelling considerations and optimization
(2021-03) Jwara, Thandeka Yvonne Sthembile; Musonge, Paul; Bakare, Babatunde F.
Wastewater treatment is a critical chain in the urban water cycle. Wastewater treatment prevents the toxic contamination of water bodies. The notable consequences of contamination are the loss of aquatic life, upsurge of eutrophication due to nutrient overload, and potential loss of human life as a result of waterborne diseases. Wastewater works (WWW) are therefore an intrinsic component of protecting the urban water cycle and ensuring that water resources are preserved for future generations. The operation of a WWW is subject to compliance with the national legislative requirements imposed by the Department of Water and Sanitation (DWS) to ensure the preservation of water resources. These requirements oblige water and sanitation departments to employ innovative design, control and optimization of WWW. Wastewater modelling packages have presented the opportunity to simulate the wastewater treatment processes in order to maintain and sustain legal compliance with the DWS. The successful implementation of a simulation package for wastewater process optimization and modelling depends on an accurate characterization also known as fractionation of the organic fractions of the WWW influents. This thesis is a result of a comprehensive study reported for Darvill wastewater work. Darvill WWW is a 60 ML/D plant which has been receiving flows of up to 120 ML/D. The importance of the study was to motivate for the upgrade of the wastewater work to account for the increased hydraulic, organic and nutrient loading into the plant. The study looked at the application of the World Engine for Simulation and Training (WEST) and all studies required to generate data that will serve as input with the understanding the current state of Darvill WWW in terms of performance. The study presents the fractionation outcomes of the primary wastewater effluent organic matter as chemical oxygen demand (COD) and the performance by assessing the biological nutrient removal process (BNR) using BNR efficiencies in addition to the development of the Darvill WWW WEST model with the aid of the probabilistic fractionator. The fractionation was achieved through the oxygen uptake rate experiments using the respirometry method. Experiments yielded the following results: biodegradable COD (bCOD) (70.5%) and inert COD (iCOD) (29.5%) of the total COD. Further characterization of the bCOD and iCOD yielded the readily biodegradable fraction (SS) at 75%, slowly degradable (XS) at 25%, particulate inert (XI) was 50.8% and the inert soluble SI at 49.2%. The COD fractions were used and served as input to the development and evaluation of the Darvill WEST model. Calculations of BNR efficiencies were used to evaluate the effects of high inflow to the biological treatability of the activated sludge for the period September 2016 - November 2017. It was found that at inflows above design capacity, the nutrient removal efficiency reduced from an expected 80-90% to an average of 40% with an average soluble reactive phosphorus (SRP) removal efficiency being 64%. A data input file for the period of January – June 2016 was created to serve as input into WEST to develop a baseline average model for the Darvill WWW plant. The model results predicted a mixed liquor suspended solids (MLSS) concentration of 6475 mg/L for the plant during the study period this was comparable with the plant MLSS concentration of 6700 mg/L at the time which was above the design concentration of 4500 mg/L. This was largely due to the plant operating under nutrient overload conditions. The final effluent (FE) concentration in the defractionation model was found to be COD = 41.28 mg/L, ammonia (NH3) = 22.02 mg/L, Total Suspended Solids (TSS) = 32 mg/L, SRP = 2.16 mg/L. Most of these results were expectedly non-compliant to the discharge limits imposed by the DWS with the exception of COD. The plant FE measurements were COD = 45.1 mg/L, NH3 = 3.4 mg/L, TSS = 20.9 mg/L, SRP= 6.67 mg/L. The COD and TSS prediction were comparable to the model prediction however there were limitations in the models ability to predict NH3 and SRP. The model does not account for changes in dissolved oxygen (DO) and temperature as these parameters are kept constant for the purpose of this study. The model assumes a temperature of 20 oC and a DO concentration of 2 mg/L for the aerobic reactor, 0.01 mg/L for the anaerobic reactor and 0.1 mg/L for the anoxic reactor. The model assumes that with the nutrient overload, oxygen compensation occurs within the reactor to maintain a constant DO concentration within the units. This limits the model in the prediction of actual instance where the overload would deplete the DO and where other competing reactions would give rise to greater non-compliances as well as biological growth’s impairment due to cold weather conditions.
Comparative study of anammox-mediated nitrogen removal in three reactor configurations
(2021-05-27) Kosgey, Kiprotich Eric; Pillai, Sheena Kumari Kuttan; Kiambi, Sammy Lewis; Bux, Faizal; Chandran, Kartik
Anaerobic ammonium oxidation (ANAMMOX) is an efficient and cost-effective process developed for biological nitrogen removal from wastewater. However, widespread application of the ANAMMOX process for wastewater treatment remains constrained due to the slow growth of ANAMMOX bacteria, propensity for out-competition by fast growing microbes, and its sensitivity to environmental and operational conditions. Consequently, understanding the influence of mixing conditions in different reactor configurations on this process is paramount in its improvement. This study focused on the comparative analysis of ANAMMOX-mediated nitrogen removal in a hybrid up-flow anaerobic sludge blanket reactor (H-UASB), moving bed biofilm reactor (MBBR) and a gas-lift reactor (GLR). The study involved experimental study of nitrogen removal, bacterial population dynamics and physical properties of the bacterial biomass within the reactors, as well as the description of process performance and the growth of nitrifying and ANAMMOX bacteria in the reactors using a calibrated mechanistic model. All the reactors were operated for 535 days using the same synthetic feed under anaerobic conditions. K1-type carrier materials were added to each reactor for biofilm development. The concentrations of ammonium (NH4 + ), nitrite (NO2 - ) and nitrate (NO3 - ) in the effluent from the reactors were determined colorimetrically. Among the three reactors, MBBR displayed the highest nitrogen removal efficiency (NRE) during the study (66±36%), and contained the lowest concentration of free ammonia (FA) (19±22 mg-N/L) and free nitrous acid (FNA) (0.001±0.001 mg-N/L). In comparison, the NRE and the concentrations of FA and FNA in H-UASB during the study were 63±28%, 91±41 mg-N/L and 0.006±0.004 mgN/L, respectively, while in the GLR, they were 54±39%, 28±29 mg-N/L and 0.002±0.002 mg-N/L, respectively. Based on the ratios of NO2 - consumed to NH4 + consumed, and the ratios of NO3 - produced to NH4 + consumed, the start-up of ANAMMOX process was faster in the MBBR (144 days) compared to H-UASB (193 days) and GLR (272 days). MBBR also displayed less fluctuations in the NREs and nitrogen removal rates (NRRs) during the study compared to H-UASB and GLR. The microbial communities in the suspended biomass in the reactors were characterised using high-throughput sequencing on an Illumina MiSeq platform on days 125, 192, 260, 309 and 535, while the microbial communities in the biofilms were only characterised on day 535 (last day) due to slow biofilm development. Gradual increases in the relative abundance of ANAMMOX bacteria were observed in the suspended biomass in all the reactors between days 125 and 309, which corroborated the observed increases in the NREs. The relative abundance of ANAMMOX bacteria remained consistently higher in H-UASB during the study than in MBBR and GLR. On the contrary, the highest relative abundance of ammonia oxidising bacteria (AOB) was observed in the suspended biomass in the MBBR on day 125 at approximately 38%, while the highest relative abundance of nitrite oxidising bacteria (NOB) and complete ammonia oxidising (COMAMMOX) bacteria was recorded in the suspended biomass in the MBBR at approximately 30% and 5%, respectively. In all the reactors, the relative abundance of AOB in the biofilms and the suspended biomass was comparable on day 535. In addition, on day 535, higher relative abundance of NOB was observed in the biofilms in both GLR and H-UASB at approximately 7% compared to the suspended biomass, while their abundance in the suspended biomass in the MBBR was comparable to that recorded in the biofilms. Furthermore, in both H-UASB and MBBR, higher relative abundance of ANAMMOX bacteria was observed in the suspended biomass compared to the biofilms on day 535, while comparable abundance was observed in the GLR. The highest total microbial diversity (Shannon and Simpson indices) and evenness (Pielou’s Evenness) was observed in the suspended biomass in the MBBR. Granulation of the suspended biomass was observed in both GLR and H-UASB, while the suspended biomass in the MBBR was flocculent. In the MBBR, the colour of the biomass had turned brown on day 125, while the biomass in H-UASB and GLR on this day was tawny and dark-tawny, respectively. However, on day 309, the biomass in all the reactors had turned red, corroborating the highest relative abundance of ANAMMOX bacteria observed during the study. Faster attachment of biomass on the carrier materials in MBBR was observed in the course of study compared to H-UASB and GLR. On the last day, the concentrations of the biomass on the carrier materials in the MBBR was also higher (12 mg/carrier) in the MBBR than in the H-UASB (8 mg/carrier) and GLR (10 mg/carrier). Activated sludge model 1 (ASM 1), which was modified by separating the activities of Nitrospira spp. from those of Nitrobacter spp. as well as by adding both ANAMMOX and COMAMMOX bacterial activities, was used to describe process performance in the reactors. The modified ASM 1 was able to predict the trends in the effluent concentrations of NH4 + , NO2 - and NO3 - in all the reactors. In addition, the correlation of the actual relative abundance of nitrifying and ANAMMOX bacteria, with the model-predicted relative abundance, was positive. The model also indicated higher heterotrophic activities in both GLR and MBBR compared to H-UASB, an indication that continuous mixing in MBBR and alternation of plug-flow conditions with internal gas circulation in GLR favoured heterotrophic bacterial growth. However, the model was limited in predicting the fluctuations in bacterial abundance and the fluctuations in the effluent concentrations of NH4 + , NO2 - and NO3 - in the reactors. The obtained results indicate that better-mixed conditions in the MBBR led to comparable relative abundance of nitrifying bacteria between the biofilms and the suspended biomass, while plug-flow conditions in the H-UASB favoured ANAMMOX bacterial growth in the suspended biomass and the nitrifying bacterial growth in the biofilms. The alternation of internal gas circulation with plug-flow conditions in the GLR also favoured the growth of nitrifying bacteria in the biofilms. Overall, nitrogen removal in H-UASB was likely dominated by ANAMMOX process, while nitrogen removal in MBBR and GLR was as a result of combined ANAMMOX and sequential nitrification-denitrification processes. The novelty of this study stem from the impact of mixing conditions on process performance and microbial ecology of ANAMMOX-mediated systems.
A comparative study of trenchless technologies versus traditional open trenching for the replacement of ageing potable water pipelines
(2014-06-13) Hay, Shanley; Macleod, Neil A.; Walker, Mark
The urgent need to rehabilitate or replace ageing deteriorated buried potable water pipeline networks is one of the many critical service utility provision challenges faced within the municipalities in South Africa. The majority of these unreliable deteriorated pipeline networks consist of un-dipped (not coated with bitumen) AC piping which have long passed their planned economic and technical lifespan. Traditionally, the open trenching method has been utilised for the replacement of aged and deteriorated piping. However, this traditional open trenching method has shown to be expensive and difficult to implement, particularly in congested high traffic use urban areas. The need to rehabilitate or replace the ageing deteriorated buried potable water pipelines in South Africa, taking into account the above mentioned expensive factors has a solution. This solution is termed ‘trenchless technology’ and sometimes also termed ‘no dig’. Recent advancements in trenchless technologies now include innovative methods such as pipe bursting, close-fit lining and sliplining. Close-fit compact pipe manufactured by Wavin Overseas B.V. was newly introduced in South Africa in 2010 for the rehabilitation of deteriorated pipelines. These trenchless methods require further research into their technical application merits, drawbacks and costs in relation to the traditional open trenching method in order to determine which method is more expensive and also least suitable. Traditionally, the ‘total cost’ associated with pipe rehabilitation or replacement projects consisted only of the direct costs. The indirect and socio-economic inconvenience costs were often ignored and resulted in costly expenses to the municipalities. However, this research will show that these indirect and socio-economic inconvenience costs must form part of the total cost of a project as it assists with the successful completion of the project without expensive unforeseen costs to the municipalities. In addition, this research will provide insight as to which indirect and socio-economic inconveniences are dominantly experienced by the public. To achieve this, a quantitative socio-economic survey questionnaire was developed. This questionnaire was aimed at residents and business owners who were affected during a project of this nature. This research study will serve as a support tool to municipalities of South Africa when selecting a pipe rehabilitation or replacement method. This support tool will provide key technical merits and drawbacks of the traditional open trenching method, pipe bursting method, close-fit compact pipe method and sliplining method. In addition, this research study will compare the ‘total cost’ of the traditional open trenching method against the trenchless pipe bursting method. The decision making process lies in the hands of the municipal technical managers. Therefore, their knowledge and experience of up to date information on trenchless methods (as well as the traditional open trenching method) is vitally important. This research provides insight as to the knowledge and experience of technical municipal staff on trenchless methods, its application and use in South Africa. A quantitative survey questionnaire was developed by the researcher. This questionnaire was aimed at technical staff in the water departments of district and local municipalities of South Africa. The results of the above questionnaire surveys formed part of the eThekwini Water and Sanitation (EWS) Feasibility study funded by the Dutch Government. When comparing the costs of the trenchless pipe bursting method against the traditional open trenching method, the results revealed that trenchless methods are undoubtedly cheaper and far less disruptive to the public. The results of the socio-economic survey revealed that trenchless methods were preferred by the public since it was less disturbing and the hindrances experienced were also far less than the traditional open trenching method. The results of the technical municipal survey questionnaire revealed that at least 50% of municipal technical staff of South Africa are not adequately informed about trenchless methods, its application and technical merits and drawbacks respectively. This survey questionnaire revealed that South Africa may be advancing over the years on the use of trenchless methods, however, more educating in the form of training, seminars and other methods of marketing must be undertaken starting at a municipal level.
Crashworthiness analysis of a composite light fixed-wing aircraft including occupants using numerical modelling
(2017) Evans, Wade Robert; Jonson, Jon David; Walker, Mark
The development and validation of reliable numerical modelling approaches is important for higher levels of aircraft crashworthiness performance to meet the increasing demand for occupant safety. With the use of finite element analysis (FEA), development costs and certification tests may be reduced, whilst satisfying aircraft safety requirements. The primary aim of this study was the development and implementation of an explicit nonlinear dynamic finite element based methodology for investigating the crashworthiness of a small lightweight fibre reinforced composite aircraft with occupants. The aircraft was analysed as it crashed into soft soil and the FEA software MSC Dytran was selected for this purpose. The aircraft considered for the purposes of this study was based on a typical four-seater single engine fibre-reinforced plastic composite aircraft. The definition of a survivable accident is given by Coltman [1] as: “an accident in which the forces transmitted to the occupant through his seat and restraint system do not exceed the limits of human tolerance to abrupt accelerations and in which the structure in the occupant’s immediate environment remains substantially intact to the extent that a liveable volume is provided for the occupants throughout the crash sequence”. From this definition, it was determined that the FEA models must primarily provide an assessment on the crashworthiness of the aircraft in terms of the structural integrity of the airframe to ensure a minimum safe occupant volume and the tolerance of humans to abrupt (de)accelerations. An assessment of other crashworthiness factors have been ignored in this study, such as post-crash hazards (e.g. fire) and safe egress for the occupants. Stockwell [2] performed a dynamic crash analysis of an all-composite Lear Fan aircraft impacting into concrete with the explicit nonlinear dynamic finite element code MSC Dytran. The structural response of components was qualitatively verified by comparison to experimental data such as video and still camera images. The composite fuselage materials were represented with the use of simplified isotropic elastic-plastic material models, and therefore did not account for the anisotropic properties of composite materials and the associated failure mechanisms. The occupants were represented as lumped masses; therefore occupant response could not be investigated. Malis and Splichal [3] performed a dynamic crash analysis of a composite glider impacting into a rigid surface with MSC Dytran; however further model verification was required. The 50th percentile adult male (occupant of average height and mass) Hybrid III anthropomorphic test device (ATD), also referred to as a crash test dummy, was represented in the analyses with the Articulated Total Body (ATB) model integrated within MSC Dytran. Various injury criteria of the ATB model were evaluated to determine the crashworthiness of the glider. Bossak and Kaczkowski [4] performed global dynamic crash analyses of a composite light aircraft crash landing. Representative wet soil, concrete and rigid impact terrains were modelled using Lagrangian-based finite element techniques and only the vertical velocity component of the aircraft was considered to simplify analyses. It was assumed that the previous use of only a downward vertical velocity component was a result of possible numerical instabilities which commonly occur with the use of Lagrangian solvers when considering problems with large deformations, which is a characteristic of crash analyses (i.e. the addition of a horizontal velocity component may result in severe element deformation of the soft soil terrain, resulting in premature analysis termination). Analyses of the occupant were performed in separate local models, using accelerations derived from the global analyses results. The real-time interactions between the occupant and aircraft therefore could not be investigated, which is considered a major disadvantage. Impact analyses of helicopters into water were performed by Clarke and Shen [5], and Wittlin et al. [6]. Both these papers showed promising results with the use of Eulerian-based finite element techniques to model the water. Additionally, combined horizontal and forward velocity components were assigned to the fuselages with success. It must be noted that the fuselages were modelled as rigid bodies; therefore the effect of structural failure on analyses could not be investigated. Fasanella et al. [7] performed drop tests of a composite energy absorbing fuselage section into water using Eulerian, Arbitrary Lagrange Eulerian (ALE) and Smooth Particle Hydrodynamics (SPH) meshless Lagrangian-based finite element techniques to represent water. Successful correlation between experimental and numerical data was achieved; however, structural failure could not be modelled with the Eulerian-based finite element technique due to analysis code limitations at the time. A “building block” approach was used in this study to develop accurate numerical modelling techniques prior to the implementation of the full-scale crash analyses. Once the blocks produced satisfactory results in themselves, they were then integrated in order to achieve the abovementioned primary aim of this study. The sub-components (or blocks) were the occupant (viz, FEA of the human bodies’ response to impact), (FEA of) soft soil impact and (FEA of) fibre-reinforced plastic composite structures. This approach is intuitive and provides key understanding of how each sub-component contributes to the full-scale crash analyses. Published literature was reviewed, where possible, as a basis for the development and validation of the techniques employed for each sub-component. The technique required to examine the dynamic response of an occupant with MSC Dytran, integrated with the ATB model, was demonstrated through the analysis of a sled test. The numerical results were found to be comparable to experimental results found in the literature. An Eulerian-based finite element technique was implemented for soft soil impact analyses, and its effectiveness was determined through correlation of experimental penetrometer drop test results found in the literature. An investigation into the performance of the Tsai-Wu failure criterion to capture the onset and progression of failure through the layers of fibre reinforced composite laminates was conducted for an impulsively loaded unidirectional laminate strip model. Based on the results obtained, the techniques implemented for each sub-component were deemed valid for crashworthiness applications (viz. to achieve the project aim). Full-scale crash analyses of impacts into rigid and soft soil terrains with varying aircraft impact and pitch angles were investigated. Typical limitations encountered in previously published works were overcome with the techniques presented in this study. The aircrafts’ laminate layup schedule was explicitly defined in MSC Dytran, thereby eliminating the inherent inaccuracies of using isotropic models to approximate laminated composite materials. The aircraft was assigned both horizontal and vertical velocity components instead of only a vertical component, which increased the model accuracy. Numerical instabilities, due to element distortion of the terrain when using a Lagrangian approach, were eliminated with the use of an Eulerian soft soil model (Eulerian techniques are typically used to model fluids where large deformations occur, which is a characteristic of crash analyses). Structural failure was successfully implemented by coupling Lagrangian and Eulerian solvers. The ATB model allowed for the real-time interactions between the occupant and aircraft to be investigated, unlike previously where analyses of the occupant were performed in separate local models using accelerations derived from the global analyses results. The results obtained from the crash analyses provide an indication of the forces transmitted to the occupant through the seat and restraint system, and the aircraft’s ability to provide a survivable volume throughout the crash event. The explicit nonlinear dynamic finite element based methodology was successfully implemented for investigating the crashworthiness of small lightweight composite aircraft, satisfying the primary aim of this study. Chapter 1 provides a review of fibre reinforced composite materials, the finite element method (FEM), ATDs and associated analysis codes, human tolerance limits to abrupt (de)accelerations, and crash dynamics and environment. The review of the FEM initially focuses on the fundamentals of FEA and then on the features specific to MSC Dytran as it is used throughout this study. Chapter 2 discusses the development of suitable numerical modelling techniques at the sub-component level and the implementation of these techniques within the full-scale crash analyses. Chapter 3 presents and discusses the full-scale crash analyses results for three impacts into rigid terrain and three impacts into soft soil terrain with varying aircraft pitch and impact angles. The results obtained from the crash analyses provide an indication of the forces transmitted to the occupant through the seat and restraint system, and the aircraft’s ability to provide a survivable volume throughout the crash event. Chapter 4 provides a conclusion of the work performed in this study and highlights various areas for future work.
Desalination of a local oil refinery effluent to meet discharge limits
(2021-12-01) Ezugbe, Elorm Obotey; Rathilal, Sudesh
The Sustainable Development Goal Six (SDG 6) – “ensure availability and sustainable management of water and sanitation for all” places huge responsibilities on stakeholders (industry, domestic and agricultural) to prioritize water saving, water reuse and proper wastewater treatment to make potable water accessible everywhere in the world. With the industrial sector consuming nearly 20% of the fresh water available, there is a corresponding generation of large volumes of effluents. This has been projected to increase, as population is skyrocketing and more economies are becoming more industrialized to accommodate the needs of the ever-increasing population. Over the years, stringent effluent discharge limits have been imposed on the industrial sector to minimize the pollution of the receiving environments, especially the water bodies. In addition, wastewater treatment for reuse is being encouraged, which will ease the stress on freshwater resources. The oil refinery industry is noted for the generation of large volumes of effluents. These effluents are heavy laden with toxic and refractory materials as well as high concentrations of salts which pose huge environmental risks and detrimental ripple effects on humans and animals if these effluents are not properly treated before discharge. Unfortunately, the use of conventional treatment methods to treat downstream oil refinery effluent (ORE) has been unsuccessful in the removal of these materials, especially the salts. This research therefore, aimed at desalinating the effluent from the effluent treatment plant (ETP) of a local South African waste oil refinery to meet discharge limits. The ETP, even though successful in the removal of organics (COD, turbidity and colour), consistently records high levels of sulphates, chlorides and carbonates as a result of the source of their raw material and other in-house processes that take place during the treatment process. The study assessed and compared the feasibility of applying three membrane processes, viz forward osmosis (FO), reverse osmosis (RO) and hybrid FO-RO systems in desalinating the ORE. The FO and RO were first run as standalone processes, where models were generated and used to optimize the important factors using the Box-Benhken design (BBD) of response surface methodology (RSM). Based on the optimized conditions, the hybrid FORO was investigated. The basis of comparison was their permeation fluxes, salt rejection and flux recoverability after membrane cleaning. A total of 45 experimental runs were conducted which catered for pure water flux tests of virgin membranes, optimization studies and confirmatory runs. The factors of interest for FO were feed solution flow rate (FS-FR) (7.5 – 9.4 L/h), draw solution flow rate (DS-FR) (7.5 – 9.4 L/h) and draw solution concentration (DS-C) (20, 35 and 50 g/L NaCl). With RO, focus was placed on operating pressure (14 – 18 bar), feed concentration and operating time (4-6 h). The results showed an average permeation flux of 3.64 ± 0.13 L/m2 h, Clenrichment (reverse solute diffusion (RSD)) of 35.5 ± 5.15%, SO4 2- rejection of 100%, CO3 2- rejection of 94.59 ± 0.32 and flux recovery of 86.01 ± 2.66% for FO. For RO, the average permeation flux achieved was 2.29 ± 0.24 L/m2 h, Clrejection efficiency was 90.54 ± 0.81%, SO4 2- rejection efficiency was 95.1%, CO3 2- rejection efficiency was 97.3 ± 0.4 and flux recovery after membrane cleaning was 62.52 ± 2.62%. The FO-RO hybrid process proved unsuccessful due to constraints from the filtration unit. As an intervention to make the hybrid process work, NF was used as the recovery process. However, results show a low permeation flux of 0.69 ± 0.10 L/m2h on average. From the results obtained, it was concluded that RO presents the best desalination option for treating the ORE using low pressure of between 14 – 18 bar. This will require no post treatment and there will be no contamination of feed due to RSD
A design methodology for the supply of subterranean water through the use of wind energy
(2005) Marais, Brett Richard
The Reconstruction and Development Programme adopted by the Government of National Unity is more than a list of the services required to improve the quality of life of the majority of South Africans. It is not just a call for South Africans to unite to build a country free of poverty and misery; it is a programme designed to achieve this objective in an integrated and principled manner. Based on the strategic objectives, as highlighted in the White Paper on Water Supply and Sanitation Policy, with regard to alleviating the chronic potable water shortages in South Africa, this thesis investigates a design methodology to supply potable water through the use of wind energy. The design focuses on small rural off-grid developments where grid electricity either has not or will not reach, and where renewable energy is the only viable option. This thesis provides an overview of wind energy and presents the fundamentals of wind power calculations. It also formulates an overview of the historic and present situation with regards to potable water supply, and reflects on the need for urgent intervention. The feasibility of using wind energy to supply potable water to rural communities in South Africa is explored in a case study. The various problem areas are identified and examined and a wide range of possible solutions are recommended. A final flow chart for the system design is proposed, thus ensuring comprehensive design methodology from which future design of similar systems can be based.