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Theses and dissertations (Engineering and Built Environment)

Permanent URI for this collectionhttp://ir-dev.dut.ac.za/handle/10321/10

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Start date: 2020Subject: search.filters.subject.Water--Pollution

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    Evaluating the removal of emerging contaminants from the eThekwini Municipality REMIX Water Treatment Plant
    (2024-05) Manyepa, Prince; Bux, Faizal; Seyam, Mahommed; Banoo, Ismail
    The eThekwini Municipalities Department of Water and Sanitation (EWS) has initiated feasibility studies to determine whether it is financially and environmentally viable to implement direct potable water reuse (DPR) projects, and one of them is the REMIX Water Treatment Plant (RWTP) which is located within the Port of Durban and abstracts wastewater and sea water for treatment and potential future re-use. However, a review of the extant literature has highlighted that wastewater and seawater are primary sources and "sinks" for various contaminants of emerging concern (CEC). Emerging contaminants (ECs) can be endocrine-disrupting chemicals or cancercausing agents in humans and animals if they are constantly present in drinking water. This study evaluated the efficiency of the RWTP for the removal of different classes of pharmaceutical compounds by measuring the feed water and effluent of each treatment unit along the RWTP. The Quantitative structure-activity relationship (QSAR) model and OPBT criteria were used to screen these compounds for persistence, bioaccumulation, and toxicity (PBT) behaviour in the water matrix. This was done to produce a priority list that allowed effective monitoring of each treatment unit for observed PBT compounds that should not be present in reclaimed water intended for human consumption. The QSAR is a suitable alternative to the costly and labourintensive in vivo screening experiments in the water matrix. It works in tandem with the new animal rights regulations, is safer than laboratory experiments, and also saves time. The study found that 4 out of 20 compounds were identified as potential PBT compounds by consensus agreement in both methodologies. The goal of this study was to assess the removal of ECs prioritised using the QSARINS model and OPBT criteria by carrying out a human risk analysis for reclaimed water proposed for drinking purposes within the City of Durban. This informed decision-makers, plant managers, and operators on what to constantly monitor or add to the treatment plant for the safe production of drinking water. Excellent removal rates of ECs were observed in the membrane biological reactor (MBR) and the reverse osmosis systems (ROs). The removal rates in MBR and ROs ranged from 38% to 100% and 96%, respectively. Excellent removal rates for heavy metals and nutrients across the treatment technology were also achieved in the final product water. The calculated risk/hazard quotients (RQ) for all ECs and heavy metals were also conducted in the reclaimed REMIX water. An RQ/HQ > 1 meant a high risk of ECs or heavy metals, and <1 meant the risk was negligible. Except for some anomalies caused by ion suppression or matrix effects during the analysis, the majority of the ECs in the reclaimed water RQ were found to be less than 1. Identification of chemical, biological, and physical hazards using HACCP system principles led to the identification of critical control points for the technology. Five critical control points were examined, and techniques for successful RWTP monitoring were proposed based on the study findings.
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    Development of a multi-criteria decision-support tool for improving water quality to assist with engineering infrastructure and catchment management
    (2024-05) Ngubane, Zesizwe; Sokolova, Ekaterina; Stenström, Thor-Axel; Dzwairo, Bloodless
    Research combining water quality modelling, quantitative chemical/microbial risk assessment, and stakeholder engagement to prioritise catchment areas facing water pollution problems to devise effective pollution mitigation strategies are limited. This research therefore aimed to address this gap by providing a practical and comprehensive framework that supports wellinformed decision-making processes in water pollution alleviation. By integrating multiple criteria and catchment aspects, this framework can assist infrastructure, operational, and ecological managers within a catchment in prioritising best management practices (BMPs) to reduce pollution and mitigate against potential resultant impacts. Given this context, uMsunduzi catchment, in KwaZulu-Natal, South Africa was chosen as a study site. UMsunduzi River is a major tributary of uMngeni River that is used for water supply to the cities of Pietermaritzburg and Durban. The study begins with the data synthesis from diverse sources of scientific data to identify chemical and microbial hazards, utilising a water quality modelling tool to map point and nonpoint source pollution in the catchment. The assessment encompasses the presence of pathogens such as Cryptosporidium and Escherichia coli (E. coli) in the catchment, with rural areas showing a greater contribution from animal sources, while urban areas are affected by impaired wastewater infrastructure. Quantitative microbial risk assessment (QMRA) was conducted, assuming no water treatment within the catchment. The investigation considered multiple exposure routes, including domestic drinking and recreational activities for both adults and children. The results indicate that the probability of infection from Cryptosporidium and E. coli exceeds acceptable levels set by South African water quality guidelines and the World Health Organization. The assessment further included a chemical risk assessment on various chemical groups, including organochlorinated pesticides (OCPs), pharmaceuticals and personal care products (PPCPs), heavy metals, nitrates, and phosphates. Elevated carcinogenic risks were observed for most OCPs, while noncarcinogenic pesticide effects pose long-term risks. Heavy metals and PPCPs are within sub-risk levels, but phosphates have notable ecological and health impacts, particularly in Inanda Dam, a key source of potable water for Durban. In this study, a unique contribution is made by incorporating both chemical and microbial risk assessment. Furthermore, the risk assessment methodology not only encompasses various chemical pollutants and exposure pathways but addresses the nuanced issue of water consumption variability between children and adults. To address these identified risks, a multi-criteria decision analysis methodology is employed to engage stakeholders in the risk management process. Affected, involved, and interested stakeholders, along with economic, environmental, and social criteria, contribute to the selection of Best Management Practices (BMPs). The Simple Multi-Attribute Rating Technique for Enhanced Stakeholder Take-up (SMARTEST) is utilised to identify suitable interventions. The study culminates in the recommendation of BMPs that aim to change behaviour, including public education on livestock grazing management, safe medication disposal, and responsible fertilizer and pesticide use. Pollution management measures, such as solid waste control and river cleanup, are suggested, along with infrastructure management improvements, like sewer system maintenance. This research strived to bridge the gap in water pollution alleviation by presenting a practical and comprehensive framework designed to support well-informed decision-making processes. This framework, with its integration of multiple criteria and considerations, stands poised to aid infrastructure, operational, and ecological managers within a catchment in prioritising BMPs aimed at reducing pollution and mitigating resultant health impacts.