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Research Publications (Engineering and Built Environment)

Permanent URI for this collectionhttp://ir-dev.dut.ac.za/handle/10321/215

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Subject: search.filters.subject.03 Chemical Sciences

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    Quantitative assessment of human health risks from chemical pollution in the uMsunduzi River, South Africa
    (Springer, 2023-10-24) Ngubane, Zesizwe; Dzwairo, Bloodless; Sokolova, Ekaterina; Moodley, Brenda; Stenstrom, Thor Axel
    A quantitative chemical risk assessment was performed using published data as well as data from the official monitoring programme for the uMsunduzi River in KwaZulu-Natal, South Africa. The chemicals assessed were organochlorinated pes- ticides (OCPs), pharmaceuticals and personal care products (PPCPs), heavy metals, and nitrates and phosphates. The water from uMsunduzi River is used locally without treatment. Consequently, the exposure routes investigated were via ingestion during domestic drinking and incidental ingestion during recreational activities, which were swimming and non-competitive canoeing, for both adults and children. For the individual chemicals, non-carcinogenic risks using the hazard quotient (HQ) and carcinogenic risks using the cancer risk (CR) were quantified. It was found that the exposed population is likely to experience non-carcinogenic effects from pesticides and phosphates, but not from PPCPs, heavy metals and nitrates. This study also found that the carcinogenic risks for OCPs were higher than the tolerable limit of 10-5, while for lead the risk was below the tolerable limit. Some of the activities that potentially contribute to chemicals onto the uMsunduzi River are sub- sistence farming, small plantations, illegal dumping, industries, and broken sewers. The findings of this study may act as the technical foundation for the introduction of pollution reduction measures within the catchment, including public education
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    Isothermal method for hydrate studies using a transparent variable volume cell
    (AIP Publishing, 2014-04) Ngema, P. T.; Nelson, W. M.; Naidoo, P.; Ramjugernath, D.; Richon, D.
    The measurements of hydrate dissociation points are generally achieved using the well-established isochoric method. This method implies determination of the total pressure of the system under study, as a function of temperature. It is quite time consuming, especially at higher pressures. Working at higher pressures requires equilibrium cells with thicker walls, which compromises on fast heat exchange. The use of a variable volume cell is therefore quite attractive as it allows for the measurements of hydrate dissociation pressure under isothermal conditions. This paper describes a transparent variable volume cell used for efficient and rapid measurements via the isothermal procedure.