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Faculty of Engineering and Built Environment

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    Fouling mitigation on a woven fibre microfiltration membrane for the treatment of raw water
    (Institution of Chemical Engineers, 2017-06) Chollom, Martha Noro; Pikwa, Kumnandi; Rathilal, Sudesh; Pillay, Visvanathan Lingamurti
    The main source of drinking water in rural areas of South Africa is surface water. Improving drinking water and sanitation facilities alone does not completely solve the problem of waterborne diseases. A novel simple gravity driven filtration unit incorporated with the woven fibre microfiltration (WFMF) membranes was developed for the treatment of raw water for drinking purposes. However, these membranes are susceptible to fouling which reduces flux permeation. This paper focused on evaluating the fouling mitigation strategies to improve on performance of the woven fibre membrane filtration unit with respect to fouling and flux recovery. The study found that the WFMF membrane fouled both internally by pore plugging and externally by adsorption and deposition on the membrane. As a result, a single flux enhancement strategy proved insufficient to maintain high flux successfully. A combination of strategies gave the best optimum conditions for flux production. Backwashing with a combination of brushing yielded the highest recovery of 187%. Soaking the membranes in 0.2% hypochlorite for an hour and thereafter by brushing them yielded 93% flux recovery. Mechanical cleaning however yielded the best result with 97% flux recovery. It was concluded that the selected strategies were the most successful strategies to prevent a sharp decline in flux due to fouling and giving high average flux for the filtration period.
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    The applicability of nanofiltration for the treatment and reuse of textile reactive dye effluent
    (AJOL, 2015) Chollom, Martha Noro; Rathilal, Sudesh; Pillay, Visvanathan Lingamurti; Alfa, Dorcas
    The main aim of the study was to test the feasibility of using nanofiltration (NF) processes for the treatment of reactive dye-bath effluents from the textile industry, in order to recover the water and chemicals (salts) for reuse purposes. The study of the reusability of nanofiltered water for dyeing has been given little or no attention. About 30% of reactive dyes remain unfixed on fibres; the unfixed dyes are responsible for the colouration in effluents. Membrane processes were employed to treat reactive dye-bath effluents to recover the salts and water. Investigations were conducted firstly with ultrafiltration (UF) used as a pre-treatment for NF. Secondly, evaluations were performed for 2 types of NF membranes (SR90 and NF90), in terms of quality of permeate produced and fluxes achieved for 2 different samples of effluent. The effect of cleaning on membrane performance was assessed. A reusability test was carried out on both permeate samples for dyeing light and dark shade recipes. The use of UF as pre-treatment to NF resulted in rejection of colloidal substances > 90% and a 15% flux improvement. Permeate from NF90 had a conductivity of 76 µS/cm and total organic carbon (TOC) of 20 mg/ℓ, as compared to SR90 which had a conductivity of 8.3 mS/cm and a TOC of 58 mg/ℓ. Light shade from NF90 gave satisfactory results on dyeing, with no colour difference. However a variation in colour was noticed when the medium sample was used to dye the light shade. Both NF permeates gave satisfactory results when used to dye the dark shades. Permeate from NF90 was within the accepted range for reuse, while permeate from SR90 had a higher salt recovery. Chemical cleaning resulted in 80% flux recovery. From the reusability test it was concluded that permeate from NF90 met the reuse criteria for feed water to the dye bath.
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    Development and evaluation of woven fabric microfiltration membranes impregnated with silver nanoparticles for potable water treatment
    (Elsevier, 2014-02-06) Mecha, C.A.; Pillay, Visvanathan Lingamurti
    Access to clean and safe drinking water is a fundamental human need, which is commonly lacking in remote rural areas. A simple gravity-fed water treatment unit was developed based on woven fabric microfiltration (WFMF) membranes. However, since these membranes are loose micro-filters, the unit has to be used in conjunction with a disinfectant. This paper explores combining the WFMF membranes with silver nanoparticles (AgNPs) using a modified chemical reduction method. The originally white membranes turned brown–yellow due to the surface plasmon resonance of silver; however, there was no significant difference in the morphology of the membranes after the impregnation with 0.0117 wt%AgNPs. The coated membranes were more hydrophilic and had higher water permeability (po0.05). Filtration of turbid water (40–700 NTU) showed that both membranes produced clear permeate (o1 NTU). Treatment of water spiked with bacteria (2500–77,000 CFU/100 mL Escherichia coli) showed that the removal efficiency of uncoated membranes was 84–91% and that of coated membranes was 100%. Accordingly, the coated membranes depicted great potential for water treatment. To the best of our knowledge, this is the first study that investigated the incorporation of AgNPs in WFMF membranes and characterized their properties.